1) Bar Due Spade: This bar cooks freshly brioches every morning sometimes they are just out of the oven and when you take a bite out if you feel as if you are in heaven.
2) Bar Cimmino: This bar at the behind of Duomo offers an amazing coffee very tasty brioches and also pasticerria. Definetly worth trying and the prices are normal.
4) Bistrot Milano Centrale: This place is my favorite when I'm in Centrale. The inside decoration is amazing, the brioches are warm and tasty and the coffee is really good. They have recently opened a store in Duomo.
5) San Carlo: This little corridor bar in San Babila is my favorite. Just looking at the brioches will make you hungry. It's slightly over priced but at least once you should try it. If you like morrachino, have it here to have a different kind of experience.
7) California Bakery: This place is famous is for the food so why not start the day with a freshly baked cake and a hot American coffee?